So I was wondering if there were any webcams in Chile. I did a bit of searching and found this site from Pucon which is supposed to have a live web cam of both Villarrica and the city. Here is the link for the cam showing Villarrica.
Villarica and Pucon
It is currently dark so I can’t tell what exactly it shows. I’ll look tomorrow.
Here is another one with a scenic view of Santiago. Santiago Skyline